Chemical properties of a para-benzyne.
نویسندگان
چکیده
5,8-Didehydroisoquinolinium ion, a para benzyne analogue, was generated in a Fourier transform ion cyclotron resonance mass spectrometer, and its reactivity toward various neutral reagents was examined. A direct comparison of the reaction kinetics of the para benzyne, a meta isomer, and analogous monoradicals, indicates that the para benzyne is a poorer electrophile but a more reactive radical than its meta isomer.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 124 41 شماره
صفحات -
تاریخ انتشار 2002